Laser microprobe for the study of noble gases and nitrogen in single grains: A case study of individual chondrules from the Dhajala meteorite   总被引：1，自引：0，他引：1  

R. R. Mahajan  S. V. S. Murty 《Journal of Earth System Science》2003,112(1):113-127

A laser microprobe capable of analysing nitrogen and noble gases in individual grains with masses less than a milligram is described. It can be used in both continuous wave (CW) mode, useful for stepwise heating of an individual grain, as well as in pulsed mode, useful for ablating material from a small selected area of a sample, for gas extraction. We could achieve low blanks (in ccSTP units) for 4He(4.8 x 10{-12}),²²Ne(1.0 x 10{-12}),³⁶Ar(1.0 x10 ^-13),⁸⁴Kr(2.9 x 10{-14}),¹³² Xe(2.6 x 10{-14}), and N (87 pg), using this system. Preliminary data for individual chondrules from the Dhajala meteorite show that noble gases and nitrogen from grains as small as 170 microgram can be analysed using the present laser microprobe setup. The amount of trapped neon in Dhajala chondrules is very small, and nitrogen in the chondrules is isotopically heavier as compared to the bulk meteorite.  相似文献   

Analyses of trace elements on quartz surfaces in sulfidic mine tailings from Kristineberg (Sweden) a few years after remediation     

B.?MüllerEmail author  M.?D.?Axelsson  B.??hlander 《Environmental Geology》2003,45(1):98-105

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass).  相似文献   

Development of airborne oil thickness measurements     

Brown CE  Fingas MF 《Marine pollution bulletin》2003,47(9-12):485-492

A laboratory sensor has now been developed to measure the absolute thickness of oil on water slicks. This prototype oil slick thickness measurement system is known as the laser-ultrasonic remote sensing of oil thickness (LURSOT) sensor. This laser opto-acoustic sensor is the initial step in the ultimate goal of providing an airborne sensor with the ability to remotely measure oil-on-water slick thickness. The LURSOT sensor employs three lasers to produce and measure the time-of-flight of ultrasonic waves in oil and hence provide a direct measurement of oil slick thickness. The successful application of this technology to the measurement of oil slick thickness will benefit the scientific community as a whole by providing information about the dynamics of oil slick spreading and the spill responder by providing a measurement of the effectiveness of spill countermeasures such as dispersant application and in situ burning.

This paper will provide a review of early developments and discuss the current state-of-the-art in the field of oil slick thickness measurement.  相似文献   

一个灵活的海洋——大气耦合环流模式   总被引：33，自引：13，他引：20  

Yu Yongqiang  Yu Rucong  Zhang Xuehong  Liu Hailong 《大气科学进展》2002,19(1):169-190

Based on the National Center for Atmospheric Research (NCAR) Climate System Model version 1(CSM-1), a Flexible coupled General Circulation Model version 0 (FGCM-0) is developed in this study through replacing CSM-1＇s oceanic component model with IAP L30T63 global oceanic general circulation model and some necessary modifications of the other component models. After the coupled model FGCM--0 is spun up for dozens of years, it has been run for 60 years without flux correction. The model does not only show the reasonable long-term mean climatology, but also reproduce a lot of features of the interannual variability of climate, e.g. the ENSO-like events in the tropical Pacific Ocean and the dipole mode pattern in the tropical Indian Ocean. Comparing FGCM-0 with the NCAR CSM-1, some common features are found, e.g. the overestimation of sea ice in the North Pacific and the simulated double ITCZ etc.The further analyses suggest that they may be attributed to errors in the atmospheric model.  相似文献   

Forecasting extreme events in the tropical Indian Ocean sector climate     

Roxana C. Wajsowicz   《Dynamics of Atmospheres and Oceans》2005,39(1-2):137

Prospects for forecasting climate variability over the tropical Indian Ocean sector, specifically extreme positive events of the Indian Dipole Mode (IDM), with lead times of a season or more are investigated using the NASA Seasonal-to-Interannual Prediction Project (NSIPP) coupled-model system. The coupled system presents biases in its climatology over the Indian Ocean sector, which include (i) warmest sea-surface temperatures (SSTs) occurring in the central equatorial basin rather than on the eastside with the eastern (western) tropical SSTs up to 1 °C too cool (warm), (ii) a too northwest lying InterTropical Convergence Zonal over the ocean in boreal fall, (iii) a thermocline shallower (deeper) than observed west of Sumatra-Java (north of Madagascar), (iv) a delay of about a month in the onset (cessation) of the southwest (southeast) monsoon in the west (east) in boreal spring (fall). These biases affect the effectiveness of the SST-clouds-shortwave radiation negative feedback, the sensitivity of SST to wind-stress perturbations, and the character of equatorial coupled ocean-atmosphere modes. Despite these biases, ensemble hindcasts of the SST anomalies averaged over the eastern and western poles of the IDM for the decade 1993–2002, which included extreme positive events in 1994 and 1997/1998, are encouragingly good at 3-months lead. The onset of the 1997/1998-event is delayed by about a month, though the peak and decay are correctly timed. At 6-months lead-time, the forecast at the eastern pole deteriorates with either positive or negative false alarms generated each boreal fall. The forecast at the western pole remains good.  相似文献   

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield     

Tom Andersen  William L Griffin   《Lithos》2004,73(3-4):271-288

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.  相似文献   

Effects of laser beam alignment tolerance on lidar accuracy   总被引：2，自引：0，他引：2  

Damir Latypov   《ISPRS Journal of Photogrammetry and Remote Sensing》2005,59(6):361-368

One of the major lidar error sources not yet analyzed in the literature is the tolerance of the laser beam alignment with respect to the scanning mirror. In this paper, the problem of quantifying these errors is solved for rotating polygon mirror type lidar systems. An arbitrary deviation of the beam from its design direction–the vector of beam misalignment–can be described by two independent parameters. We choose these as horizontal and vertical components of the misalignment vector in the body frame. Either component affects both, horizontal and vertical lidar accuracy. Horizontal lidar errors appear as scan line distortions—along and across track shifts, rotations and scaling. It is shown that the horizontal component of misalignment results in a scan line first being shifted across the track and then rotated around the vertical at the new center of the scan line. Resulting vertical lidar error, being a linear function of the scan angle, is similar to that produced by a roll bias. The vertical component of the beam misalignment causes scan line scaling and an along track shift. The corresponding vertical error is quadratic with respect to the scan angle. The magnitude of these effects is significant even at tight alignment tolerances and cannot be realistically accounted for in the conventional calibration model, which includes only range, attitude and GPS biases. Therefore, in order to attain better accuracy, this model must be expanded to include the beam misalignment parameters as well. Addition of new parameters into the model raises a question of whether they can be reliably solved for. To give a positive answer to this question, a calibration method must utilize not only ground control information, which is typically very limited, but also the relative accuracy information from the overlapping flight lines.  相似文献   

The International Laser Ranging Service and its support for IGGOS     

Michael Pearlman  Carey Noll  Peter Dunn  Julie Horvath  Van Husson  Paul Stevens  Mark Torrence  Hoai Vo  Scott Wetzel 《Journal of Geodynamics》2005,40(4-5):470

The International Laser Ranging Service (ILRS) was established in September 1998 as a service within the IAG to support programs in geodetic, geophysical, and lunar research activities and to provide data products to the International Earth Rotation Service (IERS) in support of its prime objectives. Now in operation for 5 years, the ILRS develops: (1) the standards and specifications necessary for product consistency and (2) the priorities and tracking strategies required to maximize network efficiency. The service collects, merges, analyzes, archives and distributes satellite and lunar laser ranging data to satisfy a variety of scientific, engineering, and operational needs and encourages the application of new technologies to enhance the quality, quantity, and cost effectiveness of its data products. The ILRS works with: (1) the global network to improve station performance; (2) new satellite missions in the design and building of retroreflector targets to maximize data quality and quantity and (3) science programs to optimize scientific data yield. The ILRS Central Bureau maintains a comprehensive web site as the primary vehicle for the distribution of information within the ILRS community. The site, which can be accessed at: http://ilrs.gsfc.nasa.gov is also available at mirrored sites at the Communications Research Laboratory (CRL) in Tokyo and the European Data Center (EDC) in Munich.During the last 2 years, the ILRS has addressed very important challenges: (1) data from the field stations are now submitted hourly and made available immediately through the data centers for access by the user community; (2) tracking on low satellites has been significantly improved through the sub-daily issue of predictions, drag functions, and the real-time exchange of time biases; (3) analysis products are now submitted in SINEX format for compatibility with the other space geodesy techniques; (4) the Analysis Working Group is heavily engaged in Pilot Projects as it works toward an ILRS “standard” global solution and (5) SLR has significantly increased its participation in the International Terrestrial Reference Frame (ITRF) activity, which is important to the success of IGGOS.  相似文献   

Formation of Paleoproterozoic eclogitic mantle, Slave Province (Canada): Insights from in-situ Hf and U–Pb isotopic analyses of mantle zircons     

Stefanie S. Schmidberger  Larry M. Heaman  Antonio Simonetti  Robert A. Creaser  Harrison O. Cookenboo 《Earth and Planetary Science Letters》2005,240(3-4):621-633

In-situ Hf isotope analyses and U–Pb dates were obtained by laser ablation-MC-ICP-MS for a zircon-bearing mantle eclogite xenolith from the diamondiferous Jericho kimberlite located within the Archean Slave Province (Nunavut), Canada. The U–Pb zircon results yield a wide range of ages (2.0 to 0.8 Ga) indicating a complex geological history. Of importance, one zircon yields a U–Pb upper intercept date of 1989 ± 67 Ma, providing a new minimum age constraint for zircon crystallization and eclogite formation. In contrast, Hf isotope systematics for the same zircons display an intriguing uniformity, and corresponding Hf depleted mantle model ages range between 2.1 ± 0.1 and 2.3 ± 0.1 Ga; the youngest Hf model age is within error to the oldest U–Pb date.

The Jericho eclogites have previously been interpreted as representing remnants of metamorphosed oceanic crust, and their formation related to Paleoproterozoic subduction regimes along the western margin of the Archean Slave craton during the Wopmay orogeny. Hf isotope compositions and U–Pb results for the Jericho zircons reported here are in good agreement with a Paleoproterozoic subduction model, suggesting that generation of oceanic crust and eclogite formation occurred between 2.0 and 2.1 Ga. The slightly older Hf depleted mantle model ages (2.1 to 2.3 Ga) may be reconciled with this model by invoking mixing between ‘crustal’-derived Hf from sediments and more radiogenic Hf associated with the oceanic crust during the 2 Ga subduction event. This results in intermediate Hf isotope compositions for the Jericho zircons that yield ‘fictitiously’ older Hf model ages.  相似文献   

Anthropogenic iodine-129 in seawater along a transect from the Norwegian coastal current to the North Pole     

Alfimov V  Aldahan A  Possnert G  Winsor P 《Marine pollution bulletin》2004,49(11-12):1097-1104

Variation in the concentrations of iodine-129 (129I, T1/2=15.7 Myr), a low-level radioactive component of nuclear fuel waste, is documented in surface waters and depth profiles collected during 2001 along a transect from the Norwegian Coastal Current to the North Pole. The surface waters near the Norwegian coast are found to have 20 times higher 129I concentration than the surface waters of the Arctic Ocean. The depth profiles of 129I taken in the Arctic Ocean reveal a sharp decline in the concentration to a depth of about 300-500 m followed by a weaker gradient extending down to the bottom. A twofold increase in the 129I concentration is observed in the upper 1000 m since 1996. Based on known estimates of marine transient time from the release sources (the nuclear reprocessing facilities at La Hague, France, and Sellafield, UK), a doubling in the 129I inventory of the top 1000 m of the Arctic Ocean is expected to occur between the years 2001 and 2006. As 129I of polar mixed layer and Atlantic layer of the Arctic Ocean is ventilated by the East Greenland Current into the Nordic Seas and North Atlantic Ocean, further dispersal and increase of the isotope concentration in these regions will be encountered in the near future.  相似文献